Since T100MD does not support floating point, assuming you don't use more than 1 decimal place, then use a fixed point of 1 = 0.1
A = ADC(1)*10 ' every unit represent 0.1
A = A + 25 ' Add 2.5 to A
IF A > 5 THEN
SETIO OUT1
ELSE
CLRIO OUT2 ' do you actually mean to turn OFF OUT1 and not OUT2?
ENDIF
Not too difficult isn't it? Note that the output 1 and 2 should be defined as OUT1 and OUT2 in their label name table.